Potassium (4-butoxyphenyl)trifluoroborate

Price on application

Potassium (4-butoxyphenyl)trifluoroborate – air-stable boron coupling reagent, C10H13BF3KO, CAS 850623-61-9. Price on application.

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3D model Potassium (4-butoxyphenyl)(trifluoro)borate(1-), CAS 850623-61-9, molecular formula C₁₀H₁₃BF₃KO, molar mass 256.12 g/mol
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Description

Potassium (4-butoxyphenyl)trifluoroborate is a potassium organotrifluoroborate – the tetracoordinate, air-stable counterpart of the corresponding boronic acid, built on a benzene core.

The practical argument for a trifluoroborate is stoichiometric honesty. Boronic acids equilibrate with their cyclic anhydrides (boroxines) and carry variable water, so a weighed sample is of uncertain composition. The trifluoroborate is a defined crystalline salt: it weighs what it is, tolerates air and moisture on the bench, and releases the active boron species only under the hydrolytic conditions of the reaction itself.

Key data

  • CAS number: 850623-61-9
  • Molecular formula: C10H13BF3KO
  • Molecular weight: 256.11 g/mol
  • Category: Potassium Trifluoroborates

Typical applications

  • multi-step sequences in which the boron handle must survive earlier steps untouched
  • reactions run in air, on the open bench, without glovebox handling
  • automated and parallel synthesis, where accurate solid dispensing matters
  • preparation of fluorinated biphenyls for display-grade liquid crystal blends
  • Suzuki-Miyaura coupling where a weighable, non-hygroscopic boron source is required

Ordering

This compound is supplied to order. Pricing depends on quantity and on the specification you need, so it is quoted rather than listed – send an enquiry stating the quantity and any purity or analytical requirement, and you will receive a written quotation.

Please quote CAS 850623-61-9 when enquiring, so that the correct isomer is supplied.

Handling and documentation

Supplied for laboratory and industrial use by trained personnel only. Not for use as a medicine, food, cosmetic or biocide, and not for administration to humans or animals. Safety documentation is issued with the order; this page is not a source of hazard information.

Additional information

CAS number

850623-61-9

Molecular formula

C10H13BF3KO

Molecular weight

256.11 g/mol

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Extended Bibliography (5)

  1. ★★☆☆☆ CROSSREF 🔓 OPEN ❓ unverified Miura, Takuya, Konishi, Yuko. 2021. "Suzuki-Miyaura coupling reaction of potassium aryl trifluoroborate using palladium(II) acetate." ChemSpider Synthetic Pages. https://doi.org/10.1039/sp948. link [accessed: 2026-08-25] CC0 (metadata)
  2. ★★☆☆☆ CROSSREF 🔓 OPEN ❓ unverified Molander, Gary A., Cooper, David J.. 2006. "Potassium Ethenyl Trifluoroborate." Encyclopedia of Reagents for Organic Synthesis. https://doi.org/10.1002/047084289x.rn00629. link [accessed: 2026-08-25] CC0 (metadata)
  3. ★★☆☆☆ CROSSREF 🔓 OPEN ❓ unverified Anonymous. "Linchpin Synthons: Metalation of Aryl Bromides Bearing a Potassium Trifluoroborate Moiety.". https://doi.org/10.1021/jo061324u.s001. link [accessed: 2026-08-25] CC0 (metadata)
  4. ★★☆☆☆ CROSSREF 🔓 OPEN ❓ unverified Anonymous. "Finding Rules Governing Layered Architectures of Trifluoroborate Potassium Salts in the Solid State.". https://doi.org/10.1021/acs.cgd.5b01760.s001. link [accessed: 2026-08-25] CC0 (metadata)
  5. ★★☆☆☆ CROSSREF 🔓 OPEN ❓ unverified Anonymous. "Synergistic Passivation by (Thiomorpholine-4-yl)methyl Potassium Trifluoroborate Enhances the Optoelectronic Performance of Perovskite Films.". https://doi.org/10.1021/acsami.5c23126.s001. link [accessed: 2026-08-25] CC0 (metadata)
Data from PubChemSource: PubChem (NIH)
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